Bioethanol

Bioethanol is a bio-based alcohol (C₂H₅OH) produced through the biological fermentation of carbohydrates derived from renewable agricultural feedstocks. It serves as a low-carbon substitute for fossil-based gasoline and as a versatile industrial alcohol. Due to its oxygen content, bioethanol improves combustion efficiency and reduces harmful exhaust emissions.

Feedstocks & Raw Materials

Sugar-Based Feedstocks
Sugarcane, sugar beet, molasses

Starch-Based Feedstocks
Corn (maize), wheat, cassava, sorghum

Cellulosic / Advanced Feedstocks (2G Ethanol)
Agricultural residues, bagasse, corn cobs, forestry waste, energy crops

Cellulosic bioethanol improves sustainability by avoiding food-versus-fuel conflicts.

Manufacturing Process

Feedstock Preparation
Crushing, milling, liquefaction, hydrolysis

Fermentation
Yeast converts sugars into ethanol and CO₂
30–35°C | 24–72 hours

Distillation
Produces ~95% hydrous ethanol

Dehydration
Molecular sieves, vacuum or azeotropic distillation
Final purity: 99.5–99.9% anhydrous ethanol

Grades & Specifications

Fuel Grade Bioethanol
Purity ≥ 99.5% | Petrol blending

Industrial Grade Bioethanol
Purity 95–99.9% | Chemicals, inks, coatings

Extra Neutral Alcohol (ENA)
Highly purified | Beverages & pharmaceuticals

Physical & Chemical Properties

Chemical Formula: C₂H₅OH
Density: ~0.789 g/cm³ (20°C)
Boiling Point: ~78.37°C
Flash Point: ~13°C
Energy Content: ~21–23 MJ/L
Octane Number: 108–110 (RON)

Performance Characteristics

Cleaner combustion due to oxygen content
High octane reduces engine knock
Improved throttle response in high-compression engines

Environmental & Sustainability Benefits

Up to 60–90% lower lifecycle CO₂ emissions
Reduced CO, HC, and particulate emissions
Carbon-neutral lifecycle
Rapid biodegradability

Blending Standards & Applications

E5, E10, E20, E85, E100 fuel blends
Automotive gasoline blending
Flex-fuel vehicles and generators

Industrial & Commercial Applications

Chemical solvents and intermediates
Pharmaceuticals and healthcare
Personal care and FMCG products

Storage & Handling

Stored in stainless or carbon steel tanks
Moisture-free environment required
Highly flammable – Class 3 liquid

Regulatory & Policy Landscape (India)

National Bio-Energy Mission
Ethanol Blended Petrol Programme (E20 target)
Supports energy security and farmer income

Advantages vs Limitations

Advantages
Renewable, cleaner combustion, high octane

Limitations
Lower calorific value than petrol
Hygroscopic nature
Requires compatible engines at higher blends