Boehmite Bauxite

Boehmite (γ-AlO(OH)) is an aluminium oxyhydroxide mineral and one of the three principal aluminium-bearing minerals found in bauxite ores, alongside gibbsite and diaspore. Boehmite-rich bauxite typically occurs in older or thermally altered deposits and plays a significant role in global aluminium production.

Compared to gibbsite, boehmite contains less structural water and more tightly bound hydroxyl groups. As a result, boehmite requires higher digestion temperatures and greater energy input during refining, influencing refinery design and operating costs.

Composition & Mineralogy

ParameterDescription
Chemical Formulaγ-AlO(OH)
Mineral TypeAluminium oxyhydroxide
Crystal SystemOrthorhombic
StructureLayered double octahedral sheets with hydrogen bonding
OccurrenceDisseminated or pisolitic aggregates in bauxite

Physical Properties

PropertyTypical Description
ColorWhite, pale grey, yellowish, brownish (impurity dependent)
Hardness (Mohs)~3 – 4
LusterVitreous to pearly
StreakWhite
Specific Gravity~3.00 – 3.07
CleavageGood on certain planes
Texture in OreFine-grained aggregates

Mechanical Properties

Boehmite is not a structural material; however, its mechanical behavior affects ore preparation and refining efficiency.

✔ Moderate hardness increases milling energy compared to gibbsite
✔ Brittle fracture behavior aids comminution
✔ Particle size distribution influences digestion kinetics

Strengthening & Metallurgical Behavior

Boehmite does not directly strengthen metals but plays a critical role in aluminium metallurgy as a major alumina source.

Refining Behavior:
✔ Dissolves in hot NaOH at temperatures typically above 200 °C
✔ Requires autoclave digestion (higher pressure & energy)
✔ Produces sodium aluminate solution for alumina precipitation
✔ Calcination yields Al₂O₃ for aluminium smelting

Because of its thermal stability, boehmite-rich bauxites are more energy-intensive to process than gibbsite-rich ores.

Refining & Processing Properties

Bayer Process Considerations:
✔ Higher digestion temperature and pressure
✔ Slower dissolution kinetics than gibbsite
✔ Use of additives (e.g., lime) to improve reactivity
✔ Higher energy demand balanced by alumina yield

Key Characteristics

✔ Thermally stable aluminium oxyhydroxide
✔ Higher density than gibbsite
✔ Chemically amphoteric (reacts with acids and bases)
✔ Suitable precursor for high-surface-area alumina
✔ Important feedstock for refractory and catalyst-grade aluminas

Available Forms

Natural:
Boehmite-rich bauxite ore

Processed:
Hydrated boehmite mineral
Calcined transitional aluminas (γ-Al₂O₃)
High-surface-area alumina for catalysts & adsorbents

Applications

Primary Uses:
✔ Aluminium production (Bayer process)
✔ Catalyst supports (petrochemical & refining industries)
✔ Refractories & high-temperature ceramics
✔ Abrasives & polishing compounds
✔ Flame retardants & functional fillers

Advantages of Boehmite Bauxite

✔ Reliable alumina source in suitable deposits
✔ Thermally stable mineral phase
✔ Enables production of specialty aluminas
✔ Valuable for advanced industrial materials
✔ Supports both metallurgical and non-metallurgical markets

Why Choose Boehmite Bauxite?

Boehmite bauxite is essential where it forms a major fraction of the ore. Although it requires higher processing temperatures, it delivers consistent alumina yield and enables production of high-performance alumina products for catalysts, ceramics, and refractories.

Boehmite bauxite is a strategically important aluminium ore, balancing higher refining energy with versatile industrial applications across metals, catalysts, and advanced materials.