Galvanizing Zinc

Galvanizing Zinc refers to high-purity zinc metal used as a protective coating on steel and iron to prevent corrosion. When applied through processes like hot-dip galvanizing, electro-galvanizing, or thermal spraying, the zinc forms a robust barrier that protects the base metal from rust and environmental damage.

Zinc protects steel in two ways:

1. Physical Barrier Protection
It creates a tough, adherent coating that stops moisture, oxygen, and chemicals from reaching the steel surface.

2. Cathodic (Sacrificial) Protection
Even if the coating is scratched, zinc will corrode first instead of the steel, ensuring long-term durability.

Galvanizing Zinc is widely used in construction, infrastructure, automotive, electrical, marine, and household applications.

Chemical Composition

Typical Galvanizing Zinc Composition

ElementTypical Content
Zinc (Zn)≥ 99.95%
Aluminum (Al)0.005 – 0.20%
Nickel (Ni)0.04 – 0.06% (optional)
Bismuth (Bi)0.02 – 0.10% (lead-free fluidity agent)
Lead (Pb)≤ 0.005% (or zero in eco grades)
Iron (Fe)≤ 0.003%
Cadmium (Cd)≤ 0.003%

Key Mechanical Properties

Galvanizing zinc is not used as a structural metal, but its mechanical behavior affects coating durability.

PropertyTypical Value
Tensile Strength100–150 MPa
Yield Strength30–50 MPa
Elongation10–30%
Hardness~30–40 HB
Modulus of Elasticity~108 GPa
Adhesion to SteelExcellent (metallurgical bond)

Mechanical Relevance

Zinc coating absorbs impact and abrasion

Acts as a ductile sacrificial layer

Coating remains intact during forming and bending of steel

Physical Properties

PropertyValue
Density7.13 g/cm³
Melting Point419.5°C
Boiling Point907°C
Thermal Conductivity~116 W/m·K
Electrical Conductivity~28% IACS
Coefficient of Thermal Expansion30.2 µm/m·°C
AppearanceBright silver (fresh), dull grey (aged)

Strengthening & Metallurgical Behavior

Intermetallic Layer Formation

In hot-dip galvanizing, zinc reacts with iron to form intermetallic layers:

Gamma (Γ) – Fe₃Zn₁₀
Delta (δ) – FeZn₇
Zeta (ζ) – FeZn₁₃
Eta (η) – Pure zinc outer layer

These layers:

Create a true metallurgical bond
Provide superior adhesion compared to paint or plating
Control coating hardness and durability

Strengthening Mechanism

Galvanizing zinc:

Is not heat treatable
Relies on intermetallic phase formation for functional strength
Alloying additions control layer growth and surface finish

Key Characteristics

1. Sacrificial Corrosion Protection

Zinc corrodes preferentially to steel
Protects even when coating is scratched or damaged
Offers long-term protection in harsh environments

2. Self-Healing Behavior

Zinc corrosion products seal exposed areas
Prevents under-film corrosion

3. Excellent Coating Uniformity

Controlled fluidity ensures even thickness
Reduced dross and ash formation

4. Compatibility with Various Steels

Optimized for:

Mild steel
High-silicon steel
Automotive-grade steel

Refining & Processing Properties

Produced from electrolytic zinc (SHG)
Alloyed in controlled melting furnaces
Strict impurity monitoring (Pb, Cd, Fe)

Processing Behavior in Galvanizing

Low viscosity molten zinc
Stable bath chemistry
Minimal oxidation
Good wetting of steel surface

Bath Additive Roles

Aluminum – oxidation control & adhesion
Nickel – reduces excessive coating thickness on silicon steel
Bismuth/Lead – improves drainage and surface smoothness

Available Forms

SHG zinc ingots
Galvanizing-grade alloy ingots
Jumbo blocks
Zinc slabs
Zinc shot / pellets
Custom bath alloy formulations

Applications of Galvanizing Zinc

1. Construction & Infrastructure

Structural steel
Transmission towers
Bridges
Handrails and guardrails

2. Automotive & Transportation

Body panels
Chassis components
Fasteners

3. Energy & Utilities

Power transmission structures
Wind turbine towers
Solar mounting structures

4. Agriculture & Water

Fencing
Irrigation pipes
Water tanks

Advantages of Galvanizing Zinc

✔ Long-lasting corrosion protection (20–100+ years)
✔ Complete coverage including edges and interiors
✔ Sacrificial protection even after damage
✔ Low maintenance cost
✔ Fast coating process
✔ Fully recyclable

Limitations

❌ Not a load-bearing material
❌ Performance decreases above 200°C
❌ Coating thickness influenced by steel chemistry
❌ Requires controlled bath management

Why Choose Galvanizing Zinc?

Galvanizing zinc is selected when long-term steel protection, reliability, and cost efficiency are critical.

Industries choose galvanizing zinc because it:

Extends steel life multiple times
Reduces life-cycle maintenance cost
Performs in marine, industrial, and rural environments
Offers predictable, standardized performance
Meets ASTM, ISO, EN, and IS specifications

Galvanizing zinc is a purpose-engineered zinc grade optimized for coating steel through metallurgical bonding. Its high purity, controlled alloying, sacrificial corrosion behavior, and excellent processing characteristics make it the most effective and economical solution for long-term steel protection across infrastructure, automotive, energy, and industrial sectors.