TSP – Triple Super Phosphate (0-46-0)

Triple Super Phosphate (TSP) is a high-analysis phosphatic fertilizer produced by treating phosphate rock with phosphoric acid. It contains a very high concentration of water-soluble phosphorus and supplies phosphorus in a readily available form that supports root development, flowering, and overall crop productivity.

Product Identification

ParameterSpecification
Chemical FormulaCa(H₂PO₄)₂·H₂O
Fertilizer Grade0-46-0 (N-P₂O₅-K₂O)
CategoryFully water-soluble phosphatic fertilizer (P only)
Nitrogen ContentNil
Calcium ContentPresent (secondary nutrient)
Granule ReactionAcidic

Chemical Nature

TSP is a chemically processed calcium phosphate fertilizer formed by acidulating phosphate rock with phosphoric acid. It provides highly reactive, water-soluble phosphorus without adding nitrogen.

Strengthening & Granulation Behavior

TSP granules develop mechanical strength through:

✔ Crystallization of monocalcium phosphate
✔ Controlled granulation moisture
✔ Thermal drying and curing
✔ Anti-caking surface coatings (clays, fatty amines)

📌 No metallurgical behavior applies (ionic compound)

Thermal & Chemical Behavior

Thermal Decomposition:
Loses crystal water above ~100–120 °C
Converts to dicalcium phosphate at higher temperatures
Further heating forms insoluble calcium phosphates

Chemical Reactivity:
Highly reactive in soil
Rapid phosphorus availability
Calcium buffers excessive soil acidity

Key Agronomic Characteristics

✔ High phosphorus concentration without nitrogen
✔ Immediate phosphorus availability
✔ Supplies calcium as a secondary nutrient
✔ Ideal where nitrogen is supplied separately

Manufacturing & Processing

Produced through full acidulation using phosphoric acid:

✔ Beneficiated phosphate rock
✔ Wet-process phosphoric acid
✔ Acidulation reaction
✔ Granulation, drying, screening, and coating

Key Process Controls:
Acid concentration
Rock reactivity
Free acid content
Granule moisture

Available Forms

Granular TSP (field application)
Powdered TSP (fertilizer blends & industrial use)
Bulk TSP (plantations & large farms)

Applications

Agriculture: Pulses, oilseeds, cotton, sugarcane, vegetables
Best suited for: Nitrogen-rich soils, legume crops, calcareous soils (localized effect)

Industrial: Phosphate chemical feedstock, animal feed phosphates (after processing), intermediate for compound fertilizers

Advantages of TSP

Agronomic:
✔ High P₂O₅ without nitrogen
✔ Immediate crop response
✔ Calcium improves root development
✔ Excellent for balanced nutrient programs

Commercial:
✔ Lower cost than MAP/DAP per unit phosphorus
✔ Simple, single-nutrient composition
✔ Excellent blend compatibility

Limitations & Considerations

No nitrogen or sulfur content
More hygroscopic than DAP
Dust issues if poorly granulated
Less suitable for fertigation systems

TSP vs DAP vs MAP

ParameterTSPDAPMAP
N (%)01811
P₂O₅ (%)464652
CalciumHighTraceTrace
Soil ReactionAcidicSlightly alkalineAcidic
Blend CompatibilityExcellentModerateExcellent

Why Choose TSP?

✔ Pure phosphorus source
✔ Ideal for legume crops
✔ Provides calcium supplementation
✔ Cost-effective phosphorus fertilization
✔ Flexible nutrient planning

Storage & Handling

Store in dry conditions
Avoid prolonged humidity exposure
Use moisture-resistant bags
Follow FIFO inventory practices

Soil Suitability Summary

Soil TypeSuitability
Neutral soilsExcellent
Slightly alkaline soilsGood
Highly alkaline soilsModerate
Acidic soilsUse cautiously